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[Co(NH_{3})_{5}NO_{2}]Cl_{2} ..and .. [Co(NH_{3})_{5}ONO]Cl_{2}   are related to each other as

  • Option 1)

    Geometrical isomers

  • Option 2)

    Optical isomers

  • Option 3)

     Linkage isomers

  • Option 4)

      Coordination isomers

 

Answers (1)

best_answer

As we have learned

Linkage Isomerism -

This isomerism arises in complexes containing ambidentate ligands.

- wherein

For example: \left [ Co\left ( NH_{3} \right )_{5}\left (NO_{2} \right ) \right ]Cl_{2}

Hence NO2  can connect by nitrogen and also by oxygen.

 

 

Here more than one atom function as donor, as oxygen in first one and nitrogen in second, so they show linkage isomerism

 


Option 1)

Geometrical isomers

Option 2)

Optical isomers

Option 3)

 Linkage isomers

Option 4)

  Coordination isomers

Posted by

satyajeet

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