Lanthanides form halides of the same formula but why their coordination number decreases as we move across the group?
Increase in number of unpaired electrons.
Smaller size of cation as we move across the group.
Larger size of cations as we move across the group.
Shielding effect of f-orbitals effect the coordination number.
As the cation size becomes small it can accommodate lesser number of ligands.
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