29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl's method and the evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid required 15 mL of 0.1 M solution for complete neutralization. The percentage of nitrogen in the compound is
29. 5
59.0
47.4
23. 7
As we learnt ,
Law of Definite Proportions -
A compound always contains exactly the same propotion of elements by weight
- wherein
CaCO3 contains 40% Ca, 12% C and 48% O by weight irrespective of the source.
m moles of HCl = 20 x 0.1 = 2
m moles of NaOH = 15 x 0.1 = 1.5
m moles of HCl that consumedd NH3 = 0.5
m moles of NH3 = 0.5
milligrams of N in NH3 = 0.5 x 14 = 7 mg
% N = = 23.7 %
Option 1)
29. 5
Option 2)
59.0
Option 3)
47.4
Option 4)
23. 7
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