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Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure pi and temperature T1 are connected through a narrow tube of negligible volume as shown in the figure below.  The temperature of one of the bulbs is then raised to T2.  The final pressure pf is :

  • Option 1)

    p_{i}\left ( \frac{T_{1}T_{2}}{T_{1}+T_{2}} \right )

  • Option 2)

    2p_{i}\left ( \frac{T_{1}}{T_{1}+T_{2}} \right )

  • Option 3)

    2p_{i}\left ( \frac{T_{2}}{T_{1}+T_{2}} \right )

  • Option 4)

    2p_{i}\left ( \frac{T_{1}T_{2}}{T_{1}+T_{2}} \right )

 

Answers (1)

best_answer

As we have learnt,

 

Boyle’s Law -

At constant Temp and moles, pressure is inversely proportional to volume of gas.

- wherein

P_{1}V_{1}= P_{2}V_{2}     

 

 

Charles’s Law -

At constant pressure and moles, volume is directly proportional to temperature of gas.

- wherein

\frac{V_{1}}{T_{1}}= \frac{V_{2}}{T_{2}}          

 

 

Gay Lussac’s Law -

Pressure -Temperature Relationship

- wherein

\frac{P_{1}}{T_{1}}= \frac{P_{2}}{T_{2}}

 

 

Avogadro’s Law -

Volume - mole relationship

- wherein

\frac{V_{1}}{n_{1}}= \frac{V_{2}}{n_{2}}

 

 Intitially,

n_1 = \frac{P_i V}{RT_1}, n_2 = \frac{P_i V}{RT_1}

Later on:

n'_1 = \frac{P_f V}{RT_1}, n'_2 = \frac{P_f V}{RT_2}

\\*\Rightarrow n_1 + n_2 = n'_2+ n'_2 \\*\Rightarrow \frac{P_i V}{RT_1} +\frac{P_i V}{RT_1} = \frac{P_f V}{RT_1} + \frac{P_f V}{RT_2} \\*\Rightarrow \frac{2P_iV}{RT_1} = \frac{P_f V}{R}\left(\frac{T_1 + T_2}{T_1T_2} \right ) \\*\Rightarrow P_f = \frac{2P_i T_2}{T_1 + T_2}

 

 

 

 


Option 1)

p_{i}\left ( \frac{T_{1}T_{2}}{T_{1}+T_{2}} \right )

Option 2)

2p_{i}\left ( \frac{T_{1}}{T_{1}+T_{2}} \right )

Option 3)

2p_{i}\left ( \frac{T_{2}}{T_{1}+T_{2}} \right )

Option 4)

2p_{i}\left ( \frac{T_{1}T_{2}}{T_{1}+T_{2}} \right )

Posted by

SudhirSol

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