Which of the following oxidation states of Bi is most stable?
+3
+1
+5
0
+3 oxidation state of Bi is more stable than +5 oxidation state due to inert pair effect. This is because d & f orbitals in the penultimate shells do not shield the S electrons effectively, so they are tightly bounded by nucleus therefore +3 is more stable than +5 oxidation state of Bi.