Which of the following will not react with tollen's reagent ?
Glucose
Sucrose
Fructose
Galactose
As we have learnt,
Reducing Sugars contain free aldehyde or Ketone
group (tautomerisable to an aldehyde) and are capable of reducing Fehling solution and Tollen's reagent.
Eg. Maltose, Glucose, Fructose , Galactose.
These are usually identified by a hemiacetal linkage in the cyclic Haworth representation.
Sucrose is not a reducing sugar.
Hence, the correct answer is Option (2)