Which one of these has lowest ionisation potential?
S
P
Cl
Ar
As we learnt
Variation of I.E. down the group -
Z increases with increase in atomic number, which result in the increase of force attraction between the nucleus and the outermost electron and accordingly I.E. should increase.
-
As we know as atomic no. increases ionisation potential increases but in case of sulphur there are 2 3p electrons paired. There is some repulsion between paired electrons in the same sub-level. This reduces force of attraction to the nucleus, so less energy is needed to remove one of these paired electrons than is needed to remove an unpaired electron from phosphorus