What are the limitations of VBT?
It does not explain the pairing of electrons in presence of strong ligands
It does not differentiate between strong and weak field ligands
It does not explain the effect of temperature on the magnetic properties
All of the above
Limitations of VBT -
While the Valence Bond theory, to a larger extent, explains the formation, structures and magnetic behaviour of coordination compounds, it has some shortcomings which are listed below:
(i) It involves a number of assumptions.
(ii) It does not give quantitative interpretation of magnetic data.
(iii) It does not explain the colour exhibited by coordination compounds.
(iv) It does not give a quantitative interpretation of the thermodynamic or kinetic stabilities of coordination compounds.
(v) It does not make exact predictions regarding the tetrahedral and square planar structures of 4-coordinate complexes.
(vi) It does not distinguish between weak and strong ligands.
Therefore, option (4) is correct.