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What are the limitations of VBT?

Option: 1

It does not explain the pairing of electrons in presence of strong ligands


Option: 2

It does not differentiate between strong and weak field ligands


Option: 3

It does not explain the effect of temperature on the magnetic properties


Option: 4

All of the above


Answers (1)

best_answer

Limitations of VBT -

While the Valence Bond theory, to a larger extent, explains the formation, structures and magnetic behaviour of coordination compounds, it has some shortcomings which are listed below:
(i) It involves a number of assumptions.
(ii) It does not give quantitative interpretation of magnetic data.
(iii) It does not explain the colour exhibited by coordination compounds.
(iv) It does not give a quantitative interpretation of the thermodynamic or kinetic stabilities of coordination compounds.
(v) It does not make exact predictions regarding the tetrahedral and square planar structures of 4-coordinate complexes.
(vi) It does not distinguish between weak and strong ligands.

Therefore, option (4) is correct.

Posted by

Ritika Kankaria

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