Which of the following bicarbonate is most stable ?
NaHCO3
LiHCO3
KHCO3
RbHCO3
Thermal stability and solubility stability of metal bicarbonates increase down the group.
LiHCO3 does not exist in solid-state, other bicarbonates are crystalline solid. RbHCO3 is the most stable among them.
Therefore, option(4) is correct.