Which of the following is not an ambident nucleophile?
R-OH
Ambident nucleophile -
Nucleophiles having two different nucleophiles centres are called ambident nucleophile.
For example:-
:
Now, ,
,
have two nucleophilic centres each, depending upon the reaction conditions the different side of nucleophile can be attached to a substrate. But R-OH has only one nucleophile centre (Only oxygen ) so it is not an ambident nucleophile.
Therefore, option (4) is correct.