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13.3 Account for the following:
(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions,aniline on nitration gives a substantial amount of m- nitroaniline.
Answers (1)
Nitration is carried out in strongly acidic medium, aniline is protonated to form the anilinium ion which is meta directing. Because of this reason, aniline on nitration gives a substantial amount of meta - nitroaniline
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