12.32. An organic compound contains 69% carbon and 4.8% hydrogen, the remainder being oxygen. Calculate the masses of carbon dioxide and water produced when 0.20 g of this substance is subjected to complete combustion.
Given,
Percentage of carbon = 69%
% of Hydrogen = 4.8%, and
% of Oxygen = 26.2 %
So, 0.2 g of OC have g of Carbon = 0.138g
we know that,
molecular weight of = 44 g
12 g of C is present in 44 g of
Therefore, 0.138 g of C present in = 0.506 g of
Hence, from 0.2 g of OC 0.506 g of will be produced.
Similarly,
100 g of OC contains 4.8 g of H
So, 0.2 g of OC contains = 0.0096 g of H
We know the mol. wt. of water = 18 g
Therefore 0.0096 g of H will present in = 0.0864 g of water
Hence 0.2 gram of OC will produce 0.0864 g of water on complete combustion of