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Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will, the mass of copper and silver, deposited on the cathode be the same or different? Explain your answer.

 

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According to Faraday's second law of electrolysis amount of different substance liberated by same quantity or electricity passes through electrolyte solution is directly proportional to their chemical equivalent weight.
W1/W2=E1/E2

where, E1 and E2 have different values depending upon number of electrons required to reduce the metal ion.

Hence, masses of Cu and Ag deposited will be different.

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