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Consider the following diagram in which an electrochemical cell is coupled to an electrolytic cell. What will be the polarity of electrodes ‘A’ and ‘B’ in the electrolytic cell?

 

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‘A’ has negative and ‘B’ has positive polarity.

An electrolytic cell is an electrochemical cell that utilizes an external source of electrical energy to force a chemical reaction that would otherwise not occur. The external energy source is a voltage applied between the cell's two electrodes; an anode and a cathode, which are immersed in an electrolyte solution.

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