Enthalpy diagram for a particular reaction is given in Fig. 6.3. Is it possible to decide spontaneity of a reaction from given diagram. Explain.
No, for the state of spontaneity, the enthalpy change is not the only criteria. Entropy also needs to be taken into account here.
The change in entropy (ΔS) is the best indicator of a reaction's spontaneity. The Second Law of Thermodynamics states that a reaction is spontaneous if entropy increases. Entropy measures the amount of energy dispersed during a process.
Enthalpy: Enthalpy is the sum of a system's internal energy, pressure, and volume. Enthalpy change (ΔH) can also increase or decrease randomness by affecting molecular motions.