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  • For the following bond cleavages, use curved-arrows to show the electron flow and classify each as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

12.16     For the following bond cleavages, use curved-arrows to show the electron flow and classify each as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

 (b)ORGANIC CHEMISTRY – SOME BASIC PRINCIPLES AND TECHNIQUES

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Bond cleavage by using curved-arrows to show the electron flow of the given reaction can be represented as;

It is an example of heterolytic cleavage as the bond breaks in such a manner that electron pair will remain with the carbon of propanone. The reaction intermediate is carbanion.

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