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13.14 Give plausible explanation for each of the following:
(iii) Why are aliphatic amines stronger bases than aromatic amines?
Answers (1)
Aliphatic amines stronger bases than aromatic amines due to resonance in aromatic base the lone pair of electron of N atom delocalised over the benzene ring, which makes it less available for electron donation. On the other hand, in aliphatic amines(), the electron donor group is attached which increase the electron density at N atom. Thus the aliphatic amines are more basic than aromatic amines.
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