Metal carbonates decompose on heating to give metal oxide and carbon dioxide. Which of the metal carbonates is most stable thermally?(i) $\mathrm{MgCO}_3$
(ii) $\mathrm{CaCO}_3$
(iii) $\mathrm{SrCO}_3$
(iv) $\mathrm{BaCO}_3$
The answer is the option $(i v) \mathrm{MCO}_3 \rightarrow \mathrm{MO}+\mathrm{CO}_2$
Thermal stability of $\mathrm{MCO}_3$ depends on the stability of MO. If MO is stable $\mathrm{MCO}_3$ is unstable and vice versa
BaO is the least stable making BaCO3 mthe ost stable.