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On the basis of information given below mark the correct option.

Information:

(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly the same as A–B type interactions.

(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.

(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.

(i) Solution (B) and (C) will follow Raoult’s law.

(ii) Solution (A) will follow Raoult’s law.

(iii) Solution (B) will show a negative deviation from Raoult’s law.

(iv) Solution (C) will show a positive deviation from Raoult’s law

Answers (1)

The answer is the option (ii). In a Bromoethane (A) and Chloroethane (B) mixture, the interactions A-A, B-B and A-B are nearly equal, so the solution will be nearly ideal and thus follow Raoult’s law.

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