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Why are different colours observed in octahedral and tetrahedral complexes for the same metal and same ligands?
Answers (1)
In octahedral complex, the lower wavelength of light is absorbed more than tetrahedral complex for a same metal and ligand. Formation of the d-orbital splitting is inverted in tetrahedral coordination entity and it is smaller than the octahedral field splitting. It can be shown as below for a same metal ligand.
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