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13.8     Write structures of different isomers corresponding to the molecular formula, C_{3}H_{9}N.  Write IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.

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structures of different isomers corresponding to the molecular formula C_{3}H_{9}N and their IUPAC name-

(i)

Propan-1-amine

 

(ii)

Propan-2-amine

 

(iii)

N – Methylethanamine

(iv)

N, N-Dimethylmethanamine

 

The structure (i) and (ii) will liberate nitrogen gas (N_{2}) on treating with nitrous acid.

 

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