The density of a solution prepared by dissolving 120 g of urea ( mol. Mass = 60 u ) in 1000g of water is 1.15 g/mL.
The molarity of this solution is :
0.50 M
1.78 M
1.02 M
2.05 M
Mass of solute taken = 120 g
Molecular mass of solute = 60 u
Mass of solvent = 1000 g
Density of solution =1.15 g/mL
Total mass of solution = 1000 +120 + =1120 g
Option 1)
0.50 M
Option 2)
1.78 M
Option 3)
1.02 M
Option 4)
2.05 M
Study 40% syllabus and score up to 100% marks in JEE
The idea here is that a solution's molarity tells you the number of moles of solute present in 1 L of solution.
So in order to calculate a solution's molarity, you essentially need to know the number of moles of solute present in exactly 1 L=103 mL of solution.
Start by using the molar mass of urea to calculate the number of moles present in your sample
120g*1 mole urea/60g=2 moles urea
Now, you know that your solution contains 120 g of urea, the solute, and 1000 g of water, the solvent. This implies that the total mass of the solution
mass solution = mass solute + mass solvent
will be equal to
mass solution=120 g + 1000 g=1120 g
You also know that this solution has a density . of 1.15 g mL−1, which means that every 1 mL of solution has a mass of 1.15 g.
Use the density of the solution to calculate its volume
1120g*1 mL/1.15g=973.9 mL
Now, your goal is to figure out the number of moles of solute present in 103 mL of solution, so use the known composition of the solution as a conversion factor to get
103mL solution*2 moles urea/973.9mL solution=2.0536 moles urea
You can thus say that the molarity of the solution is equal to
molarity = 2.05 mol L−1