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The increasing order of nitration of the following compounds is :

  • Option 1)

    (b) < (a) <  (c) < (d)

  • Option 2)

    (a) < (b) <  (c) < (d)

  • Option 3)

    (b) < (a) < (d) < (c) 

  • Option 4)

    (a) < (b) < (d) < (c) 

 

Answers (1)

As we learnt in 

Gabriel Phthalimide Synthesis -

Further alkylation can be stopped and a pure primary amine can be obtained by alkylation of phthalimide ( Gabriel synthesis ) followed by hydrolysis.

- wherein

 

 

Here the aniline is least reactive due to formation of anilinium ion in acidic medium. 

 


Option 1)

(b) < (a) <  (c) < (d)

Option 2)

(a) < (b) <  (c) < (d)

Option 3)

(b) < (a) < (d) < (c) 

Option 4)

(a) < (b) < (d) < (c) 

Posted by

Vakul

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