Castner-kellner cell is used for manufacturing NaOH. The cathode in this cell is made up of :
Fe
C
Hg
Ni
Preparation of NaOH by the Castner-Kellner cell is also known as mercury cathode process of electrolysis of brine solution
cathode:
Anode:
In the castner - kellner cell , used to manufacture NaOH, graphite rods are used as anodes and Mercury acts as cathode.
Therefore, option(3) is correct.