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  • Arrange the following: (iii) (b) C_6H_5NH _2

13.4     Arrange the following:    

                (iii) In increasing order of basic strength:

                 (b) C_{6}H_{5}NH_{2},    C_{6}H_{5}NHCH_{3},    C_{6}H_{5}CH_{2}NH_{2}.

 

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The increasing order of basic strength-    C_{6}H_{5}NH_{2}<C_{6}H_{5}NHCH_{3}<C_{6}H_{5}CH_{2}NH_{2}

C_{6}H_{5}NHCH_{3}, it is more basic than aniline due to the presence of one electron donating group which increases the electron density at N atom. And also in this compound N atom is directly attached with the benzene ring, so due to -R effect C_{6}H_{5}NHCH_{3}, is less basic than C_{6}H_{5}CH_{2}NH_{2}.

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manish

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