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13.4     Arrange the following in increasing order of their basic strength:

               (ii)  C_{2}H_{5}NH_{2}, (C_{2}H_{5})_{2}NH, (C_{2}H_{5})_{3}N, C_{6}H_{5}NH_{2}

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C_{6}H_{5}NH_{2}<C_{2}H_{5}NH_{2}<(C_{2}H_{5})_{3}N<(C_{2}H_{5})_{2}NH

On considering the inductive effect, solvation effect and steric hindrance of the alkyl group the increasing order of basicity in ethyl as a substituted group is shown above.

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