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Which of the following alkyl halides will undergo S_N1 reaction most rapidly?

(a) (CH_3)_3C-F

(b) (CH_3)_3C-Cl

(c) (CH_3)_3C-Br

(d)(CH_3)_3C-I

Answers (1)

(d) (CH_3)_3C-I will undergo S_N1 reaction most readily. Here, the C-l bond is the weakest because the size difference between carbon and iodine is huge.

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