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Which of the following methods of preparation of amines will not give the same number of carbon atoms in the chain of amines as in the reactant?

(i) The reaction of nitrite with $LiAlH_{4}$ .

(ii) The reaction of the amide with $LiAlH_{4}$ followed by treatment with water.

(iii) Heating alkyl halide with potassium salt of phthalimide followed by hydrolysis.

(iv) Treatment of amide with bromine in the aqueous solution of sodium hydroxide.

Answers (1)

Option (iv) is the correct answer.

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infoexpert23

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