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Distinguishing reagent between silver and lead salts is

Option: 1

\\\mathrm{H}_{2} \mathrm{S} \; \text{gas}\\


Option: 2

Hot dilute \mathrm{HCl} solution


Option: 3

\mathrm{NH}_{4} \mathrm{Cl} \: \text{(solid)} +\mathrm{NH}_{4} \mathrm{OH} \:\: \text{solution}


Option: 4

\mathrm{NH}_{4} \mathrm{Cl} \: \: \text{(solid)} +\left(\mathrm{NH}_{4}\right)_{2} \mathrm{CO}_{3}\: \: \text{solution}


Answers (1)

best_answer

As we have learnt, 

Both \text{Pb}^{2+} \text{ and } \text{Ag}^{+} belong to Group 1 of basic radicals and form white precipitates of their respective chlorides.

But \mathrm{PbCl}_{2} is soluble in hot water while \mathrm{AgCl} does not dissolve in hot water.

So, hot and dilute \mathrm{HCl} will be able to distinguish between the given ions.

Hence, the correct answer is Option (2)

Posted by

Ritika Jonwal

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