What is the nature of glucose-glucose linkage in starch that makes it so susceptible to acid hydrolysis?
Starch is hemiacetal
Starch is acetal
Starch is polymer
Starch contains only few molecules of glucose
Because of the presence of glycosidic linkage
Starch is made up two components both of which have different structures:
• Amylose
• Amylopectin
Starch is an acetal. It is made up of long chains of glucose molecules held together by glycosidic bonds (an ether linkage). This linkage can be easily broken through acid hydrolysis which releases constituent glucose molecules. The H+ of the acid attacks the oxygen of glycosidic bonds which leads to destabilisation and hydrolysis of the bond.
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