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Which of the following should be most volatile?

(i) II

(ii) IV

(iii) I

(iv) III

Answers (1)

Option (ii) is the correct answer.

Explanation: The boiling points of 1° and 2° amines are higher than 3° amines because of intermolecular H-Bonding. They are also less volatile than 3° amines and hydrocarbons of similar molecular mass.

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