An acidic buffer contains a weak acid and its salt.
Here,
Given the weak acid is CH3COOH and its salt will be CH3COONa
So,
100 mL of 0.1 M HCl = 10 meq HCl
200 mL of 0.1 M CH3COONa = 20 meq of CH3COONa
After mixing 10 meq of HCl react with 10 meq of CH3COONa then 10meq of CH3COOH form.
But from other options, the same amount of weak acid and its salt cannot be obtained.
Finally, 10meq of CH3COOH and 10 meq of CH3COONa will be present.
So upon mixing 100ml of 0.1M HCl and 200ml of 0.1M CH3COONa, a buffer solution will be obtained.
Therefore, Option(2) is correct.
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