The metal d-orbitals that are directly facing the ligands in are:
Strong Field Ligand -
These are the ligands which pair the electron in inner d-orbital and makes required d-orbitals empty/available.
- wherein
For example: CO, CN etc
Stability of Complex -
Stability of complex is depends on nature of ligands, size of central atom and stability concept.
- wherein
Stability Stability Constant
Crystal field splitting in tetrahedral complexes -
orbitals has more value of energies as compared to .
- wherein
As we learn
We have learned in comlex compounds
fig
Octahedral geometry , hybridisation
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co in +3 oxidation state and that too with a strong field ligand forms OCTAHEDRAL complex acc to VBT . therfor electrons of the ligand should enter through Eg instead of T2g . therefore acc to iit professors here , ans should be dxy,dyz,dzx ,.... SBGM