Which of the following has highest melting point?
P
As
Sb
Bi
As we learn
Melting and Boiling Point do not show a regular trend due to difference in bonding type in metal and non-metals
Metal point is the factor which depends on the intermolecular forces. For melting down, we need to break the Van-der-wall forces between molecules. Nitrogen exists as N2 containing 2 moleclues while phosphorus exists as P4 ( 4 molecules). Energy required to break the Vanderwall force increases with the increase in number of moleclues.
As has metallic nature, due to increase in metallic nature of elements going down, e- become loose causing weak interaction. So, MP increases upto As and then decreases down.
Therefore, option (3) is correct.