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The appropriate reagent for the following transformation:

Option: 1

Zn(Hg)/HCl


Option: 2

NaBH_{4}


Option: 3

H_{2}/Pd\: \: BaSO_{4}, Quinoline


Option: 4

NH_{2}NH_{2},\: OH^{-}


Answers (1)

best_answer

Rosenmund's reaction -

Acid chlorides are reduced in boiling xylene using Pd / Pt along with BaSO4, S or quinoline is used to poison  Pd / Pt to stop the reduction of aldehyde further.

RCOCl_{2}+H_{2}\rightarrow RCHO+HCl

Reaction:-

 

Therefore, Option(3) is correct

Posted by

vinayak

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