Which of the following is the intermediate unstable salt in Hofmann bromamide reaction or Hofmann degradation of Acetamide?
Hoffmann Bromamide Reaction -
Amides on reaction with Br2 or Cl2 in alkali give 1o amine with one C atom less than the parent amide. This is known as Hofmann bromamide rearrangement or degradation reaction. The reaction occurs as follows:
From the mechanism it is evident that the unstable intermediate salt in the Hoffman's degradation reaction of Acetamide is
Hence, the correct answer is Option (4)
Study 40% syllabus and score up to 100% marks in JEE
Ask your Query
Register to post Answer