Q.64) Given below are two statements :
Statement I : Ferromagnetism is considered as an extreme form of paramagnetism.
Statement II : The number of unpaired electrons in a $\mathrm{Cr}^{2+}$ ion $(\mathrm{Z} \subseteq 24)$ is the same as that of a Nd ${ }^{3+}$ ion $(\mathrm{Z}=60)$.
In the light of the above statements, choose the correct answer from the options given below :
A) Statement I is false but Statement II is true
B) Both Statement I and Statement II are true
C) Both Statement I and Statement II are false
D) Statement I is true but Statement II is false
Ferromagnetism is considered an extreme form of paramagnetism. This is a true statement.
$\mathrm{Cr}^{2+}$ and $\mathrm{Nd}^{3+}$ have same unpaired electrons.
- $\mathrm{Cr}^{2+}:[\mathrm{Ar}] 3 \mathrm{~d}^4 \rightarrow 4$ unpaired electrons
- $\mathrm{Nd}^{3+}:[\mathrm{Xe}] 4 \mathrm{f}^3 \rightarrow 3$ unpaired electrons
So they do not have the same number of unpaired electrons .
Hence, the correct answer is option (4).