Q.72) Given below are two statements :
Statement 1 : Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at $273-278 \mathrm{~K}$. It decomposes easily in the dry state.
Statement II: Insertion of iodine into the benzene ring is difficult, and hence iodobenzene is prepared through the reaction of benzenediazonium salt with KI.
In the light of the above statements, choose the most appropriate answer from the options given below :
A) Statement I is incorrect but Statement II is correct
B) Both Statement I and Statement II are correct
C) Both Statement 1 and Statement II are incorrect
D) Statement I is correct but Statement II is incorrect
Insertion of iodine into the benzene ring is indeed difficult. So iodobenzene is prepared via a Sandmeyer-type reaction from diazonium salt using KI.
Benzenediazonium salt is prepared at 273–278 K. This temperature range (0–5°C) is used to stabilize the diazonium ion during its formation, as higher temperatures can lead to its decomposition. It does not decompose easily in the dry state.
Hence, the correct answer is option (1).