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13.8     Accomplish the following conversions:

                (vii) Aniline to p-bromoaniline

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Aniline on reacting with the acetic anhydride in the presence of pyridine it gives N-phenylethanamide which on further reacting with Br_{2}/CH_{3}COOH the NHCOCH_{3} group direct the bromine to the para- position and after hydrolysis, we can recover the  original NH_{2} group at the same position 

 

 

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