8.7 What is lanthanoid contraction? What are the consequences of lanthanoid contraction?

Answers (1)

On moving along the lanthanoid series, the atomic number is gradually increased by one. It means the no. of electrons and protons of the atom is also increases by one. And because of it the effective nuclear charge increases (electrons are adding in the same shell, and the nuclear attraction overcomes the interelectronic repulsion due to adding of a proton). Also, with the increase in atomic number, the number of electrons in orbital also increases. Due to the poor shielding effect of the electrons, the effective nuclear charge experienced by an outer electron is increased, and also the attraction of the nucleus for the outermost electron is increased. As a result, there is a gradual decrease in the atomic size as an increase in atomic number. This is known as lanthanoid contraction.

Consequences of Lanthanoid contraction-

  • Similarities in the properties of second and third transition series
  • Separation of lanthanoid can be possible due to LC.
  • Due to LC, there is variation in basic strength of hydroxide of lanthanoid. (basic strength decrease from La(OH)_{3}-Lu(OH)_{3}).

 

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