BCl3 is more stable because there is absence of d- and f-electrons in boron, only three valence electrons (2s2 2px1) are there for bonding with chlorine atom.
In Tl the valence s-electron (6s2) are experiencing maximum inert pair effect. Thus, only 6p1 electron is available for bonding. Therefore, BCl3 is stable but TlCl3 is comparatively unstable.