Write the slope value obtained in the plot of Vs. time for a first-order reaction.
For first order reaction.
ln[R] = −kt + ln[R]0
ln[R]0 - ln[R] = kt
ln {[R]0/[R]} = kt
2.303 log {[R]0/[R]} = kt
= kt/2.303
Hence slope is k/2.303
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