10.4 Find out the oxidation state of sodium in Na_{2}O_{2}

10.5 Explain why is sodium less reactive than potassium

10.6 Compare the alkali metals and alkaline earth metals with respect to (i) ionisation enthalpy (ii) basicity of oxides and (iii) solubility of hydroxides

10.7 In what ways lithium shows similarities to magnesium in its chemical behaviour?

10.8 Explain why can alkali and alkaline earth metals not be obtained by chemical reduction methods?

10.9 Why are potassium and cesium, rather than lithium used in photoelectric cells?

10.10 When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.

10.11 Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why ?

10.12 Discuss the various reactions that occur in the Solvay process.

10.13 Potassium carbonate cannot be prepared by Solvay process. Why ?

10.14 Why is Li_{2}CO_{3} decomposed at a lower temperature whereas Na_{2}CO_{3} at higher temperature?

10.15 Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals. (a) Nitrates (b) Carbonates (c) Sulphates.

10.16 Starting with sodium chloride how would you proceed to prepare (i) sodium metal (ii) sodium hydroxide (iii) sodium peroxide (iv) sodium carbonate ?

10.17 What happens when (i) magnesium is burnt in air (ii) quick lime is heated with silica (iii) chlorine reacts with slaked lime (iv) calcium nitrate is heated ?

10.18 Describe two important uses of each of the following : (i) caustic soda (ii) sodium carbonate (iii) quicklime.

10.19 Draw the structure of (i) BeCl_{2} (vapour) (ii) BeCl_{2} (solid).

10.20 The hydroxides and carbonates of sodium and potassium are easily soluble in water, while the corresponding salts of magnesium and calcium are sparingly soluble in water. Explain?

10.21 Describe the importance of the following : (i) limestone (ii) cement (iii) plaster of paris.

10.22 Why are lithium salts commonly hydrated and those of the other alkali ions usually anhydrous?

10.23 Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone ?

10.24 Explain the significance of sodium, potassium, magnesium and calcium in biological fluids

10.25 What happens when (i) sodium metal is dropped in water ? (ii) sodium metal is heated in free supply of air ? (iii) sodium peroxide dissolves in water ?

10.26 Comment on each of the following observations: (a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb+ < Cs+ (b) Lithium is the only alkali metal to form a nitride directly. (c) E 0 for M2+ (aq) + 2e– → M(s) (where M = Ca, Sr or Ba) is nearly constant.

10.27 State as to why (a) a solution of Na2CO3 is alkaline ? (b) alkali metals are prepared by electrolysis of their fused chlorides ? (c) sodium is found to be more useful than potassium ?

10.28 Write balanced equations for reactions between (a) Na2O2 and water (b) KO2 and water (c) Na2O and CO2 .

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