Which of the following statements is not correct for a nucleophile?
Nucleophile is a Lewis acid
Ammonia is a nucleophile
Nucleophiles attack on less e- density sites
Nucleophiles are not electron seeking
As we learnt in
Nucleophile -
Those e- rich chemical species having capacity to attack e-deficient portion of substrate.
- wherein
Nucleophile must have complete octet and atleast one lone pair
Nucleophiles are those compounds which has a lone pair of electron . Lewis acid has deficiency of electron. Hence a nucleophile can't be a Lewis acid.
Option 1)
Nucleophile is a Lewis acid
Correct
Option 2)
Ammonia is a nucleophile
Incorrect
Option 3)
Nucleophiles attack on less e- density sites
Incorrect
Option 4)
Nucleophiles are not electron seeking
Incorrect
View Full Answer(1)The number of structural isomers possible from the molecular formula C3H9N is:
4
5
2
3
As we learnt in
Isomerism in nitro compounds -
Nitroalkanes shows chain, position, functional isomerism and Tautomerism.
-
Option 1)
4
Correct
Option 2)
5
Incorrect
Option 3)
2
Incorrect
Option 4)
3
Incorrect
View Full Answer(1)An electron moves on a straight line path XY as shown. The abcd is a coil adjacent to the path of electron What will be the direction of current if any, induced in the coil?
adcb
The current will reverse its direction as the electron goes past the coil
No current induced
abcd
Faraday’s First Law -
Whenever the number of magnetic lines of force (Magnetic Flux) passing through a circuit changes an emf called induced emf is produced in the circuit.
-
Initially electron is approaching the coil and then its leaving the coil. Hence first flux will increase and then decrease. Direction as electron goes past the coil.
Option 1)
adcb
This is incorrect option
Option 2)
The current will reverse its direction as the electron goes past the coil
This is correct option
Option 3)
No current induced
This is incorrect option
Option 4)
abcd
This is incorrect option
View Full Answer(1)Reaction of phenol with chloroform in presence of dilute sodium hydroxide finally introduces which one of the following functional group?
-CH2Cl
-COOH
-CHCl2
-CHO
Reimer Tiemann's reaction -
The electrophile used is CCl2 (Dichloromethylene) -CHO is introduced in the ortho position.
- wherein
Option 1)
-CH2Cl
This option is incorrect
Option 2)
-COOH
This option is incorrect
Option 3)
-CHCl2
This option is incorrect
Option 4)
-CHO
This option is correct
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Which of the following reaction(s) can be used for the preparation of alkyl halides?
(I)
(II)
(III)
(IV)
(I), (III) and (IV) only
(I) and (II) only
(IV) only
(III) and (IV) only
As we learnt in
Alcohols reaction with hydrogen halides -
Forms alkyl halides.
- wherein
Tertiary alcohols forms alkyl halides but not easily due to the higher stability of tertiary carbocation
Option 1)
(I), (III) and (IV) only
This solution is correct
Option 2)
(I) and (II) only
This solution is incorrect
Option 3)
(IV) only
This solution is incorrect
Option 4)
(III) and (IV) only
This solution is incorrect
View Full Answer(1)Which of the following statements is not correct for a nucleophile ?
Nucleophile is a Lewis acid
Ammonia is a nucleophile
Nucleophiles attack low e- density sites
Nucleophiles are not electron seeking
As we learnt in
Nucleophile -
Those e- rich chemical species having capacity to attack e-deficient portion of substrate.
- wherein
Nucleophile must have complete octet and atleast one lone pair
Nucleophiles are those having capacity to donate electrons s.e they, Lewis base
Option 1)
Nucleophile is a Lewis acid
This option is correct.
Option 2)
Ammonia is a nucleophile
This option is incorrect.
Option 3)
Nucleophiles attack low e- density sites
This option is incorrect.
Option 4)
Nucleophiles are not electron seeking
This option is incorrect.
View Full Answer(1)Method by which Aniline cannot be prepared is :
hydrolysis of phenylisocyanide with acidic solution.
degradation of benzamide with bromine in alkaline solution.on.
reduction of nitrobenzene with H2/Pd in ethanol.
potassium salt of phthalimide treated with chlorobenzene followed by hydrolysis with aqueous NaOH solution.
As we learnt in
Gabriel Phthalimide Synthesis -
Further alkylation can be stopped and a pure primary amine can be obtained by alkylation of phthalimide ( Gabriel synthesis ) followed by hydrolysis.
- wherein
Gabrief Alkalimide synthesis of primary amines.
Because there exist partial double between chlorine and carbon.
Option 1)
hydrolysis of phenylisocyanide with acidic solution.
Incorrect
Option 2)
degradation of benzamide with bromine in alkaline solution.on.
Incorrect
Option 3)
reduction of nitrobenzene with H2/Pd in ethanol.
Incorrect
Option 4)
potassium salt of phthalimide treated with chlorobenzene followed by hydrolysis with aqueous NaOH solution.
Correct
View Full Answer(1)A gas such as carbon monoxide would be most likely to obey the ideal gas law at:
high temperatures and low pressures.
low temperatures and high pressures.
high temperatures and high pressures.
low temperatures and low pressures.
As we learned in concept no
Kinetic Theory of Gases -
Molecules of gases are very small and their actual volume is negligible in comparision to the empty space between them.
-
Ideal gas behaviour is based on the following assumption
molecules of gases are very small and their actual volume is negligible in comparision to the empty space between them
There is no force of attraction between the particle of a gas at ordinary temperature and pressure
These assumptions are only valid at high temperatures and low pressures
Option 1)
high temperatures and low pressures.
This option is correct
Option 2)
low temperatures and high pressures.
This option is incorrect
Option 3)
high temperatures and high pressures.
This option is incorrect
Option 4)
low temperatures and low pressures.
This option is incorrect
View Full Answer(1)Point masses m1 and m2 are placed at the opposite ends of a rigid rod of length L, and negligible mass. The rod is to be set rotating about an axis perpendicular to it. The position of point P on this rod through which the axis should pass so that the work required to set the rod rotating with angular velocity is minimum, is given by :
As we learned in concept
Moment of inertia for system of particle -
- wherein
Applied when masses are placed discretely.
Total M.I of rod
As I is minimum i.e.
=>
Option 1)
this is the incorrect option
Option 2)
this is the incorrect option
Option 3)
this is the correct option
Option 4)
this is the incorrect option
View Full Answer(1)An automobile moves on a road with a speed of 54 km h-1. The radius of its wheels is 0.45 m and the moment of inertia of the wheel about its axis of rotation is 3 kg m2. If the vehicle is brought to rest in 15 s, the magnitude of average torque transmitted by its brakes to the wheel is :
8.58 kg m2 s-2
10.86 kg m2 s-2
2.86 kg m2 s-2
6.66 kg m2 s-2
As we learned in concept
Analogue of second law of motion for pure rotation -
- wherein
Torque equation can be applied only about two point
(i) centre of motion.
(ii) point which has zero velocity/acceleration.
V=54 Km/hr = 15m/s
Angular velocity of vehicle V=W0r
Angular Accn
=>
Option 1)
8.58 kg m2 s-2
This option is incorrect.
Option 2)
10.86 kg m2 s-2
This option is incorrect.
Option 3)
2.86 kg m2 s-2
This option is incorrect.
Option 4)
6.66 kg m2 s-2
This option is correct.
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Answer please! Which of the following statements is not correct for a nucleophile?
Solve! The number of structural isomers possible from the molecular formula C3H9N is:
Help me understand! - Alcohols, Phenols and Ethers - NEET
Can someone explain Which of the following statements is not correct for a nucleophile ?
Please help! Method by which Aniline cannot be prepared is :
Give answer! - Motion of System Of Particles and Rigid Body - NEET