Electron gain enthalpy with negative sign of fluorine is less than that of chlorine due to :
High ionization enthalpy of fluorine
Smaller size of chlorine atom
Smaller size of fluorine atom
Bigger size of 2p orbital of fluorine
The negative electron gain enthalpy of fluorine is less than that of chlorine. It is due to the small size of the fluorine atom. As a result, there are strong interelectronic repulsions in the relatively small 2p orbitals of fluorine and thus, the incoming electron does not experience much attraction.
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