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Electron gain enthalpy with negative sign of fluorine is less than that of chlorine due to :

Option: 1

High ionization enthalpy of fluorine 


Option: 2

Smaller size of chlorine atom 


Option: 3

Smaller size of fluorine atom 


Option: 4

Bigger size of 2p orbital of fluorine 


Answers (1)

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The negative electron gain enthalpy of fluorine is less than that of chlorine. It is due to the small size of the fluorine atom. As a result, there are strong interelectronic repulsions in the relatively small 2p orbitals of fluorine and thus, the incoming electron does not experience much attraction.

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Divya Prakash Singh

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