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In the chain rearrangement of allyl phenyl ether, an intramolecular rearrangement occurs to form the ortho and para derivative of allyl phenol. Consider the reaction given below. ( C* represents labelled carbon)

A and B respectively are-

Option: 1

Option: 2

Option: 3

Option: 4

Answers (1)


The intramolecular pericyclic mechanism takes place to form the products shown above. The formation of para isomer takes via the ortho isomer.

Hence, the correct option is (1).

Posted by

Kuldeep Maurya

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