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In which of the following pairs the two species are not isostructural ?

Option: 1

CO_{3}^{2-}\: and \: NO_{3}^{-}


Option: 2

PCl_{4}^{+}\: and \: SiCl_{4}


Option: 3

PF_{5}\: and \: BrF_{5}


Option: 4

AlF_{6}^{3-}\: and \:SF_{6}


Answers (1)

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\mathrm{PCl_{4}^{+}\, and\, SiCl_4\Rightarrow both \; tetrahedral}

\mathrm{PF_{5}\Rightarrow trigonal \; bipyramidal}

\mathrm{BrF_{5}\Rightarrow square \; pyramidal}

\mathrm{AIF_{6}^{3-}\, and\, SF_{6}\; both\; are \; octahedral}

\mathrm{CO_{3}^{2-}and\, NO_{3}^{-} \ both \, \, are\; trigonal\; planar.}

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Ajit Kumar Dubey

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