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\mathrm{PCl_{5}} is well known, but \mathrm{NCl_{5}} is not. Because,

Option: 1

nitrogen is less reactive than phosphorous.


Option: 2

nitrogen doesn't have d-orbitals in its valence shell.


Option: 3

catenation tendency is weaker in nitrogen than phosphorous.


Option: 4

size of phosphorous is larger than nitrogen.


Answers (1)

best_answer

\mathrm{PCl}_{5} well known, but \mathrm{NCl}_{5} is not because nitrogen doesn't have d-orbitals in its valence shell. So nitrogen cannot make 5 bonds and cannot expand its octet.

Option (2) is correct.

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manish

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