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The dark purple colour of \mathrm{\mathrm{KMnO}_{4}} disappears in the titration with oxalic acid in acidic medium. The overall change in the oxidation number of manganese in the reaction is :

Option: 1

5


Option: 2

1


Option: 3

7


Option: 4

2


Answers (1)

best_answer

In Acidic medium permagnate ion \mathrm{(MnO_{4}^{-})} act as oxidizing agent reducing itself to \mathrm{Mn^{2+}} ion.

Balanced reaction is

\mathrm{\begin{array}{r} \mathrm{MnO}_4^{-}+8 \mathrm{H}^{+}+5 e^{-} \longrightarrow \mathrm{Mm}^{2+}+4 \mathrm{H}_2 \mathrm{O} \\ \end{array}}

\mathrm{2 \mathrm{MnO}_4^{-}+5 \mathrm{C}_2 \mathrm{O}_4^{2-}+16 \mathrm{H}^{+} \longrightarrow 2 \mathrm{Mm}^{2+}+10 \mathrm{CO}_2+8 \mathrm{H}_2 \mathrm{O}}

Hence, the correct answer is Option (1).

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