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The rate constant (k) of a reaction is measured at different temperature (T), and the data are plotted in the given figure. The activation energy of the reaction in \mathrm{k J mol { }^{-1}} is: (R is gas constant)

Option: 1

3R


Option: 2

5R


Option: 3

4R


Option: 4

2R


Answers (1)

\mathrm{\begin{aligned} k & =A e^{-E a / R T} \\ \ln k & =\ln A-\left(\frac{E a}{R}\right) \frac{1}{T} \\ \ln k & =\ln A-\left(\frac{E a}{R \times 10^3}\right) \frac{10^3}{T} \end{aligned}}

slope of graph 

\mathrm{\begin{aligned} & \frac{-E a}{R \times 10^3}=\frac{-15}{5} \\ & E a=3 R \times 10^3 \mathrm{~J} \\ & E a=3 R \mathrm{~kJ} \end{aligned}}

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Sumit Saini

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